A coordinative saturated vanadium containing metal organic framework that shows a remarkable catalytic activity

K. Leus, I. Muylaert, V. Van Speybroeck, G.B. Marin, P. Van der Voort
Studies in Surface Science and Catalysis
175, 329-332


A completely saturated Metal Organic Framework, MIL-47 was synthesized and tested for its catalytic performance in the oxidation of cyclohexene with tert-butyl hydroperoxide as oxidant. The catalyst was compared to several reference catalysts: namely VAPO-5, supported VOx/SiO2 and the homogeneous catalyst VO(acac)2. MIL-47 shows a remarkable catalytic activity and preserves its crystalline structure and surface area after a catalytic run. Furthermore MIL-47 exhibits a very high activity in successive runs.